Preheat the oven to 350, and grease up a bundt pan real good.
In a large mixing bowl, whisk together flour, sugar, malted milk powder, cocoa, baking soda, baking powder, and salt.
Add egg, oil, and buttermilk all together and whisk well. Add the hot water and whisk until the batter is smooth, it will be runny - that is ok. Pour into the greased bundt pan. Since this is a runnier batter, lightly tap the pan on the counter - this will bring any bubbles to the top and get rid of them.
Bake for 55 - 60 minutes. The cake will be pulled away from the sides, and a toothpick inserted to the center will come out clean. Let it cool completely and make the glaze.
To make the glaze
Combine the butter, cream, brown sugar, corn syrup, cocoa, and salt in a small saucepan over medium heat and bring to a simmer. Simmer on low, stirring, for 3 to 5 more minutes after everything has melted, then remove from heat and stir in espresso morsels and chocolate. Stir in vanilla.
Notes
When the cake is cooled, drizzle the warm sauce over the cake.